Saturable absorption in NV-doped diamond studied by femtosecond Z-scan

Abstract

We investigate nonlinear optical absorption in diamond crystals containing high densities of nitrogen vacancy (NV) centers using open-aperture Z-scan measurements with 230 fs laser pulses at 1032 nm, within the transparency window of diamond. While high-purity electronic-grade diamond exhibits third-order nonlinear absorption, NV-doped samples display pronounced saturable absorption that strengthens with increasing defect concentration. Linear transmission spectroscopy reveals that, in addition to NV centers, the crystals host significant populations of H2 (NVN-) defect complexes whose absorption band partially overlaps the excitation wavelength. By correlating spectroscopic data with nonlinear measurements and modeling the response using an effective two-level system, we show that the observed saturation cannot be attributed solely to NV centers but arises from the combined contribution of NV-related and H2 defects. For the highly doped sample, we determine an effective linear absorption coefficient of alpha0 = 6.52 cm-1 and a saturation intensity of Is = 40.0 GW/cm2. These findings highlight the critical role of the complex defect landscape in governing the nonlinear optical response of NV-doped diamond and underscore the necessity of accounting for ancillary defect species in the design of diamond-based nonlinear and quantum photonic devices.