Influence of Markovianity and self-consistency on time-resolved spectral functions of driven quantum systems

Abstract

We present a systematic comparison of the real-time Dyson expansion (RTDE) with established non-equilibrium Green's function approaches for simulating driven, interacting quantum systems. Focusing on density matrix dynamics, time-off-diagonal Green's functions, and time-resolved photoemission spectra, we benchmark RTDE against fully self-consistent Kadanoff-Baym equation (KBE) calculations, the generalized Kadanoff-Baym ansatz (GKBA), and exact diagonalization for small systems using second order many-body perturbation theory. Using a driven two-band Hubbard model, we show that mean-field single particle density matrix trajectories provide a reliable baseline for RTDE across a broad range of interaction strengths and excited-carrier populations. Further, RTDE accurately captures correlation effects in the Green's functions, including long-lived oscillations and revivals that are strongly suppressed by the overdamping inherent to self-consistent KBE schemes. As a consequence, RTDE resolves rich non-equilibrium spectral structure in time-resolved photoemission, such as interaction- and population-dependent quasiparticle splittings and bandgap renormalization, which are largely washed out in self-consistent approaches, yet are present in the exact solutions. Our results demonstrate that RTDE bridges the gap between mean-field propagation and full two-time KBE simulations, retaining favorable linear scaling while capturing essential dynamical correlations relevant for ultrafast spectroscopy.