Time Reversal Symmetry Breaking and Fragile Magnetic Superconductors

Abstract

Roughly twenty reports (as of 2025) of time-reversal-symmetry breaking (TRSB) states in low critical temperature (Tc) superconducting (SC), otherwise conventional Fermi liquid, metals have emerged primarily from muon spin relaxation (μSR) data. The detected fields, inferred from the current interpretation of depolarization data, are similar in magnitude and not far above the lower limit of detection, corresponding to magnetizations of no more than 10-3 μB/atom. These materials comprise a new class of fragile magnetic superconductors modeled as triplet pairing. The measured SC state properties, excepting only the fields detected below Tc, are representative of low Tc singlet BCS SCs, not showing unusual coherence lengths or critical fields. While it is recognized that the muon does affect the sample by displacing nearby atoms and impacting magnetic interaction parameters, the measurement process, changing the system from sample → sample+μ+ thereby breaking TRS, may deserve further scrutiny. This overview provides a survey of the environment of the muon, from the normal state to the superfluid state, where the induced supercurrent and Yu-Shiba-Rusinov gap states provide coupling of the muon moment to the superfluid. The unusual topological superconductor LaNiGa2, currently modeled as non-unitary triplet, is used as a case study. Supposing that the prevailing μSR inference of a small spontaneous field within the bulk of theSC obtains, the current picture of (possibly non-unitary) triplet pairing is discussed and an attractive alternative for LaNiGa2 is noted.

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