Local composition controls pattern formation in conserved active emulsions

Abstract

Phase separation in passive systems leads to uncontrolled droplet growth, limiting structural control in soft materials and cells. We identify a generic mechanism to arrest coarsening based on chemical interconversion between molecular species with different diffusivities. Sharp-interface theory and simulations show that when the faster-diffusing species becomes enriched inside droplets, composition gradients emerge that oppose mass influx. This transport asymmetry stabilizes droplet sizes even without interaction asymmetries, offering a minimal route to regulate structure formation in active emulsions.