Eigenvalue asymptotics of M\"uller minimizers for atoms and molecules

Abstract

We study the spectral properties of minimizers of the M\"uller functional for atoms and molecules with $N$ electrons and total nuclear charge $Z$. We prove that under some suitable assumptions on $Z$ and $N$, the $k$-th eigenvalue of a M\"uller minimizer $\gamma_*$ behaves as $A_* k^{-8/3}$ when $k\to \infty$, with a constant $A_*>0$ determined explicitly by the density of $\gamma_*$. In particular, in the atomic case $V=Z|x|^{-1}$ our assumption holds if $Z$ is sufficiently large and $N\le Z- C_0 Z^{1/3}$. While our proof is inspired by Sobolev's work on the asymptotic behavior of the one-particle density matrix of Schr\"odinger ground states, the analysis in M\"uller theory requires several new ingredients concerning both the singular behavior of the integral kernel of the minimizers near the diagonal and the decay properties at infinity.