Generalized Shift Vector as the Intrinsic Dipole of Many-Body Correlated Electronic States

Abstract

Shift vectors play a central role in nonlinear optics and transport phenomena, where they are usually understood as charge-center shifts associated with transitions between quantum states. Here we show that the same geometric structure can be more fundamentally understood as the intrinsic dipole moment of a single correlated state. Our derivation clarifies the local and global aspects of gauge invariance, the origin of the phase-gradient term, and its connection to the internal coherence structure of many-body correlations. The single-state shift character appears both as a displacement of the real-space joint probability density and as a linear electric-field modification in energy space. Applying this framework to optically induced correlations, electron-phonon-mediated processes, and excitonic electron-hole states, we recover previously proposed shift vectors and the standard expression for the shift current as special cases. Our results establish a common physical foundation for shift vectors as intrinsic dipolar properties of correlated electronic states.