Multiplet-Selective Photoelectron Diffraction from an Altermagnet

Abstract

Direct real-space probes of altermagnetic order remain scarce. Here we introduce multiplet-selective photoelectron diffraction (PED), a methodology in which different regions of a transition-metal core-level multiplet act as distinct photoemission source waves. Using multiple-scattering calculations for the metallic altermagnet candidate CrSb, we show that selected Cr $3p$ multiplet features with predominantly $Y_1^{+1}$ and $Y_1^{-1}$ character generate robust diffraction asymmetries sensitive to altermagnetic domains. We demonstrate that both circularly and linearly polarized light provide access to the effect, while suitable combinations of domains, light polarizations, and multiplet-energy windows suppress nonmagnetic diffraction backgrounds. The proposed approach can be implemented using standard momentum-resolved photoemission instrumentation and establishes core-level PED as a practical route toward domain-resolved studies of altermagnets.