Co-adsorption mechanism drives CO oxidation on defective ZnS

Abstract

Reactivity on wide-bandgap semiconductor surfaces relies critically on the generation of active sites. In the case of CO oxidation, however, the mere presence of defects is insufficient to drive reactivity. Here, we investigate CO oxidation on a defective ZnS single-crystal surface by combining near ambient pressure X-ray photoelectron spectroscopy (NAP-XPS) and density functional theory (DFT) calculations. NAP-XPS measurements reveal CO$_2$-like surface intermediates only under oxygen-rich conditions, consistent with oxygen-assisted CO oxidation. DFT calculations support an oxygen-assisted co-adsorption pathway in which CO interacts preferentially with adsorbed oxygen species stabilized near Zn-deficient sites, forming weakly bound CO$_2$-like structures. These results identify oxygen coverage, rather than defect density alone, as the key factor controlling CO$_2$-like intermediate formation on defective ZnS and establish defective ZnS as a model platform for studying oxygen-assisted surface chemistry on non-oxide semiconductors.