Quenching of Nonrelativistic p-Wave Spin Splitting by Reduced c-f Coupling in CeNiAsO
Abstract
The application of spin-space group symmetries to noncollinear antiferromagnets has led to the prediction of odd-parity, nonrelativistic spin splittings, making the physical realization of a practical p-wave magnet a central pursuit in spintronics. The layered heavy-fermion oxypnictide CeNiAsO has been widely regarded as a prototypical platform to verify this paradigm. Here, we investigate the electronic structure of single-crystal CeNiAsO using high-resolution, ultra-low-temperature and resonant angle-resolved photoemission spectroscopy (ARPES), and ab-initio calculations. Across the consecutive magnetic transitions into the ordered phases, our spectroscopic data reveal neither the expected band folding associated with a spin density wave nor any observable p-wave spin splitting, demonstrating that the conduction bands retain full degeneracy. By tracking the temperature dependence of the Ce 4f spectral weight via resonant ARPES, we find negligible c-f hybridization near the Fermi level within magnetically ordered states, confirming that the Ce 4f electrons reside close to the localized limit. Our findings establish a clear many-body constraint on the projection of real-space magnetic symmetries onto momentum-space electronic bands, demonstrating that symmetry classifications constitute a necessary framework but are not a sufficient condition for nonrelativistic spin splittings in the presence of strong electronic correlations.
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