Spin-chiral electron-phonon coupling in metallic strontium titanate

Abstract

Electron-phonon coupling (EPC) - the interaction between conduction electrons and quantized atomic vibrations - plays a central role in condensed matter physics and determines some of the most important properties of materials, such as electrical resistivity and superconductivity. Conventionally, EPC is assumed to be induced by the ionic electrostatic background, and electronic spin plays no role in the process. In stark contrast with this view, here we uncover a direct spin-mediated coupling mechanism between electrons and transverse polar phonons in a metal. Using far-infrared light absorption measurements of the model system SrTiO$_3$ in a magnetic field, we observe a strong spin-mediated EPC that is quantitatively consistent with recent theoretical predictions, and that generates chiral phonon modes with large effective magnetic moments. The extracted coupling strength is in good agreement with ab initio estimates and sufficiently high to explain superconductivity in SrTiO$_3$, thereby resolving a long-standing conundrum. Spin-chiral EPC should generically appear in all metals with polar phonons, and the present work could be of relevance to spintronics applications and to uncovering the origins of superconductivity in layered materials, metals with Dirac points in their electronic dispersions, and nearly ferroelectric superconductors.