A population view of transiting hot giant exoplanets: Tracing Fe and Ti chemistry with ESPRESSO and MAROON-X

Abstract

Hot and ultra-hot Jupiters offer a unique laboratory to study atmospheric chemistry at the population level using ground-based high-resolution spectroscopy. Fe and Ti are key tracers of thermal and chemical structure, yet they exhibit different observational trends across the population. We present a homogeneous reanalysis of high-resolution transmission spectra of ten hot and ultra-hot Jupiters observed with VLT/ESPRESSO and Gemini-N/MAROON-X. We search for neutral Fe and Ti absorption and perform injection-recovery tests using models spanning a range of Ti-depletion levels and T-p profiles. For direct comparison across observations, we introduce the relative cross-correlation metric, $Δ$Ti-Fe. We detect Fe in 7 and Ti in 4 planets above 5$σ$. Across the population, $Δ$Ti-Fe decreases sharply towards lower equilibrium temperatures. Under the assumption of equal Ti depletion across planets, isothermal models fail to reproduce this trend, instead requiring a temperature-dependent depletion of Ti that increases toward cooler planets, consistent with cold-trapping processes in cooler atmospheres. Models with inverted T-p profiles naturally reproduce the decline without invoking temperature-dependent depletion. There, Ti is converted into TiO in deeper, cooler layers and then removed from the gas phase through condensation, leading to strong suppression of the observable atomic Ti signal. Nevertheless, even in the gradient models, overall depletion of Ti relative to Fe is required to match the hottest planets. Our results demonstrate that observable refractory chemistry is governed by the interplay of molecular partitioning, ionisation, condensation, and cold-trapping processes, as well as the vertical structure of ultra-hot Jupiter atmospheres. Additional observations will be necessary to distinguish between temperature-dependent cold-trapping and overall depletion.(abbrev.)