Hybrid Electronic-Ionic Ferroelectricity in Superlubric van der Waals Heterostructures

Abstract

One strategy to lower the switching barrier in a sliding ferroelectric (sFE) is to insert an incommensurate spacer to reduce sliding friction, creating a superlubric sliding ferroelectric (SL-sFE). However, how polarization survives across the effectively decoupled outer layers remains an open question. We show that SL-sFEs are fundamentally different from conventional sFEs: polarization is not driven by sliding alone, but by an intricate coupling between interlayer sliding and the out-of-plane buckling of the spacer layer. This coupling results in a unique hybrid electronic-ionic polarization arising from asymmetric orbital hybridization. The interplay of these order parameters generates several distinct types of ferroelectric hysteresis, including mixed first- and second-order transitions, multi-step switching, and antiferroelectric-like behavior, establishing SL-sFEs as a distinct class of ferroelectrics.