Hydration-controlled twist forms a moiré glass in charge-frustrated layered silicates

Abstract

Twisting layered materials produces moiré superlattices, but prescribed twist angles are usually obtained by demanding assembly procedures. Here we show that montmorillonite, an abundant swelling clay, forms tunable moiré superlattices naturally. Focal-series high-resolution transmission electron microscopy, geometric phase analysis, and molecular dynamics simulation reveal that its apparent rotational disorder is biased toward low-angle misorientations inherited from discrete hydration states. Multilayer stacks preferentially adopt twists near 1-2°, 4°, and 10°, producing long-wavelength moirés without long-range rotational order. We define this kinetically trapped state as a moiré glass, distinct from featureless turbostratic stacking. Simulations indicate that lattice-charge disorder stabilizes the angular preferences, whereas charge ordering promotes random stacking. Hydration screens interlayer interactions and lubricates twist, while dehydration arrests the resulting configurations in discrete steps. These results establish dynamic hydration as a macroscopic handle for programming twist in layered matter.