Bode-Fano Limits to Broadband Absorption by Small Particles

Abstract

Nanostructures can be designed to absorb light efficiently at resonance despite their subwavelength footprint, but causality and passivity fundamentally limit the bandwidth over which strong absorption can be maintained. Here we derive fundamental absorption-bandwidth limits for passive, causal, linear, and temporally dispersive subwavelength objects by rigorously casting electromagnetic scattering as an equivalent impedance-matching problem. This mapping yields ultimate Bode-Fano-type constraints for optical absorption and provides rational synthesis guidelines for the material dispersion of passive nanoparticles that can approach the bounds. Our results clarify the ultimate limits for broadband light harvesting and dissipation, with implications for solar-energy conversion, photothermal hyperthermia, thermal management, and related nanophotonic technologies.