Universal behavior of the condensation energy of Superconducting BCS Bose gases

Abstract

Using the Boson-Fermion formalism of superconductivity we calculate the condensation energy for several superconductors ranging from conventional to unconventional, or high temperature superconductors. It is calculated as the difference between the Helmholtz free energies of the superconducting and the normal state, which is a gas of N attractive electron gas, while the superconducting state is formed by the condensed Cooper pairs taken as composite bosons, coming from a fraction of the electrons inside the Debye shell, plus those electrons inside and outside the Debye shell that are unable to pair. After giving the analytic expressions for the internal energy U and the entropy S we obtain the Helmholtz free energy F = U -TS for both the superconducting and the normal states as functions of temperature. In the search for universalities, we calculate the ratio of the condensation energy at T=0 to the Sommerfeld constant (the normal state electronic specific heat over the temperature when T it's almost zero) using two different methods: the Boson-Fermion formalism developed here, as well as an analytical expression deduced from a combination of the BCS and Ginzburg-Landau theories. We find for the Boson-Fermion formalism $E_{cond}/γ_0= 0.252\,T_{c}^{1.997}$, which is the same behavior described by the experimental fit of Kim et al $E_{cond}/γ_0= 0.2\,T_{c}^{2.06}$ and by the one recently reported by Tallon et al for overdoped cuprate superconductors; while for the Ginzburg-Landau-BCS we get the expression $E_{cond}/γ_0= 0.236\,T_{c}^{2}$, also in very good agreement with the partifirst method.