Low-lying $D$ states in yttrium and actinium ions highly sensitive to variation of the fine structure constant

Abstract

Whether fundamental constants vary over time or space is one of the key questions in metrology and cosmology. Among them, variation of the fine structure constant $α$ is intensively investigated. Yttrium ions Y$^+$ and actinium ions Ac$^+$ have low-lying $D$ states that are suitable for this search, with a proper path for laser cooling and detection. Theoretical calculations show that the sensitivities of the transitions between the ground state and the lowest $^3D_1$ states are $K=9.40$ and $K=9.73$, respectively. By driving the transition between the ground state and the $^3D_1$ states with a two-photon transition, the transition can be used for a high-sensitivity search for time variation of the fine structure constant. The high efficiency of a detection scheme using the transition between the $7s6d~^3D_1$ states and the $7s7p~^3P_0$ state also suggests that Ac$^+$ ions are potentially useful as a platform for quantum information processing.