How is Water released in Hydrogen-Based Metal Oxide Reduction? Unraveling the Kinetic Bottleneck in Sustainable Metal Production

Abstract

Hydrogen-based direct reduction of metal oxides is a ubiquitous solid-gas redox process central to geophysics, sustainable metallurgy, redox energy cycles and catalysis. During this process, hydrogen removes lattice oxygen to form water, yet product water has long been regarded as a passive exhaust, and its nanoscale formation, trapping and removal remain poorly understood. Here, we directly observe redox-product water release from iron oxide during hydrogen-based direct reduction. Because water removal emerges from coupled structural, chemical and crystallographic evolution across multiple length-scales under realistic non-equilibrium reaction-conditions, we establish a correlative multiscale in-situ approach that links pore evolution, molecular water signatures, phase transformation and chemical-state evolution during hematite reduction. We uncover a mechanism in which oxygen removal induces closed nanopores spatially delocalized from reaction surfaces, causing transient trapping of water vapor. Water is released only when these pores coalesce into a percolating network connected to the surface, coinciding with and accelerating the onset of the hematite-to-magnetite transformation. These findings show that dynamically evolving pore topology governs mass transport and redox kinetics in solid-gas reactions, closing a critical mechanistic gap in product-water removal and providing nanoscale guidance for hydrogen-based metal extraction, reactor design, and sustainable redox energy technologies under practical conditions.