Searching for the elusive CH2+ with the James Webb Space Telescope. Another carbocation to constrain astrochemical networks

Abstract

Carbocations are key species in interstellar chemistry, providing entry points for building larger hydrocarbons. CH+, and more recently, CH3+, have been detected. Other carbocations await detection to provide a comprehensive view of the astrochemical network that is at work in the interstellar medium. We search for CH2+ in objects in which CH3+ was detected and evaluate the most favorable conditions for detecting the elusive CH2+ reactive cation. We calculated the CH2+ rotational and rovibrational transitions expected to contribute in the mid- to far-infrared, focusing on the lower-energy rovibrational levels. We then calculated CH2+ infrared emission spectra at different excitation temperatures and compared them to JWST spectra of the externally irradiated disk d203-506 in Orion, where CH+ and CH3+ have already been detected. We used thermochemical models to predict the abundance and spatial morphology of CH2+ to better understand its nondetection. The comparison to JWST spectra allowed us to provide excitation-temperature-dependent upper limits to the excited column density. These are several times lower than those detected for CH+ and CH3+ in their excited states. Based on model calculations for photodissociation regions and assuming similar excitation temperatures, the upper limit derived from observations and CH2+ model spectrum is either slightly above or below the column density expected from models of photodissociation regions. We provide a list of tabulated transitions to allow the community to search for this carbocation in future observations as CH2+ is key in providing observational constraints on astrochemical models.