Origin of the reaction temperature in solid-state materials synthesis

Abstract

Temperature plays a crucial role in solid-state materials synthesis, but there is currently no mechanistic theory to explain or predict which temperature is best to conduct a solid-state reaction. Reactions between powder precursors are conventionally assumed to be slow diffusion-limited processes; however, recent in situ experiments show that solid-state reactions can complete in minutes above a critical onset temperature. Here, we present evidence that a transient liquid phase forms above the metastable eutectic temperature, and that this non-equilibrium liquid serves as a fast diffusion medium to intermix precursors and initiate a solid-state reaction. This thermodynamic principle is agnostic to the structure or chemistry of the reactants, and can be applied towards the synthesis and manufacturing of a wide range of complex materials.