The critical radius of compressible capillary drops: viscosity, thermodynamics, and diffuse-interface scales

Abstract

A compressible capillary drop differs from an incompressible one in that its radius is a dynamical degree of freedom. When the drop is sufficiently small, this spherical mode can become unstable, defining a critical radius set by the competition between surface tension and compressibility. This paper examines the robustness and physical meaning of that critical radius. For a non-relativistic viscous fluid, starting from the viscous compressible equations and the free-surface stress condition, we derive the radial dispersion relation and show that shear and bulk viscosities change the eigenvalues but not the onset radius. A thermodynamic argument identifies the same radius as the point where the energy of a uniformly compressed drop changes from locally stable to unstable, explaining why the threshold is not set by viscous dissipation. This energetic interpretation can also be applied to a special-relativistic fluid, where the non-relativistic mass-density factor is replaced by the corresponding enthalpy-density factor. We then compare the critical radius with diffuse-interface length scales in two Cahn--Hilliard free-energy models to determine whether the instability can occur within the range of validity of the sharp-interface description. In a symmetric quartic model the critical radius is much smaller than the interface thickness, so the instability is absent throughout that range. In a shallow-well model, however, the critical radius can become parametrically larger than the interface thickness, leaving a range of sharp-interface drops that are unstable. Whether such a range exists therefore depends on the diffuse-interface free-energy model.