Collective Diffusion and a Random Energy Landscape
Abstract
Starting from a master equation in a quantum Hamiltonian form and a coupling to a heat bath we derive an evolution equation for a collective hopping process under the influence of a stochastic energy landscape. There results different equations in case of an arbitrary occupation number per lattice site or in a system under exclusion. Based on scaling arguments it will be demonstrated that both systems belong below the critical dimension dc to the same universality class leading to anomalous diffusion in the long time limit. The dynamical exponent z can be calculated by an ε = dc-d expansion. Above the critical dimension we discuss the differences in the diffusion constant for sufficient high temperatures. For a random potential we find a higher mobility for systems with exclusion.
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