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Magnetism and Electronic Structure in ZnFe2O4 and MnFe2O4

D. J. Singh, M. Gupta, R. Gupta

cond-matarXiv:cond-mat/0108176

Abstract

Density functional calculations are used to study magnetic and electronic properties of the spinel ferrites, ZnFe2O4 and MnFe2O4. Correct magnetic orderings are obtained. ZnFe2O4 is predicted to be a small gap insulator in agreement with experiment. MnFe2O4 is found to be a low carrier density half-metal in the fully ordered state. However, strong effects on the electronic structure are found upon partial interchange of Fe and Mn atoms. This indicates that the insulating character may be due to Anderson localization associated with the intersite Mn-Fe disorder.

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