Magnetic Raman scattering of the ordered tetrahedral spin-1/2 clusters in Cu2Te2O5(Br(1-x)Clx)2 compounds
Abstract
Raman light-scattering experiments in the antiferromagnetic phase of the Cu2Te2O5(Br(1-x)Clx)2 compounds are analyzed in terms of a dimerized spin model for the tetrahedral Cu-clusters. It is shown that the longitudinal magnetic excitation in the pure Br system hybridizes with a localized singlet excitation due to the presence of a Dzyaloshinskii-Moriya anisotropy term. The drastic change of the magnetic scattering intensities observed when a proportion of Br is replaced by Cl ions, is proposed to be caused by a change of the magnetic order parameter. Instead of being parallel/antiparallel with each other, the spins in the two pairs of spin-1/2 order perpendicular to each other, when the composition x is larger than about 0.25.
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