Non-ergodic Intensity Correlation Functions for Blinking Nano Crystals

Abstract

We investigate the non-ergodic properties of blinking nano-crystals using a stochastic approach. We calculate the distribution functions of the time averaged intensity correlation function and show that these distributions are not delta peaked on the ensemble average correlation function values; instead they are W or U shaped. Beyond blinking nano-crystals our results describe non-ergodicity in systems stochastically modeled using the Levy walk framework for anomalous diffusion, for example certain types of chaotic dynamics, currents in ion-channel, and single spin dynamics to name a few.