Conductivity, weak ferromagnetism and charge instability in α-MnS single crystal

Abstract

The temperature dependence of resistivity, magnetization and electron-spin resonance of the α- MnS single crystal were measured in temperature range of 5 K < T < 550 K. Magnetization hysteresis in applied magnetic field up to 0.7 T at T=5 K, 77 K, 300 K, irreversible temperature behavior of magnetization and resistivity were found . The obtained data were explained in terms of degenerate tight binding model using random phase approximation. The contribution of holes in t2g and eg bands of manganese ions to the conductivity, optical absorbtion spectra and charge instability in α -MnS were studied. Charge susceptibility maxima resulted from the competition of the on-site Coulomb interaction between the holes in different orbitals and small hybridization of sub-bands were calculated at T=160 K, 250 K, 475 K.

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