Study on successive superconducting transitions in Ta$_{2}$S$_{2}$C from electrical resistivity and nonlinear AC magnetic susceptibility

Abstract

Ta$_{2}$S$_{2}$C compound undergoes superconducting transitions at $T_{cl} = 3.60 \pm 0.02$ K and $T_{cu} = 9.0 \pm 0.2$ K. The nature of successive superconducting transitions has been studied from electrical resistivity, linear and nonlinear AC magnetic susceptibilities. The resistivity $ρ$ at $H$ = 0 shows a local maximum near $T_{cu}$, a kink-like behavior around $T_{cl}$, and reduces to zero at below $T_{0}$ = 2.1 K. The $\ln T$ dependence of $ρ$ is observed at $H$ = 50 kOe at low temperatures, which is due to two-dimensional weak-localization effect. Below $T_{cu}$ a two-dimensional superconducting phase occurs in each TaC layer. The linear and nonlinear susceptibilities $χ_{1}^{\prime\prime}$, $χ_{3}^{\prime}$, $χ_{5}^{\prime}$, and $χ_{7}^{\prime}$ as well as the difference $δχ$ ($= χ_{FC} - χ_{ZFC}$) between the FC and ZFC susceptibilities, start to appear below 6.0 K, the onset temperature of irreversibility. A drastic growth of the in-plane superconducting coherence length below 6.0 K gives rise to a three-dimensional superconducting phase below $T_{cl}$, through interplanar Josephson couplings between adjacent TaC layers. The oscillatory behavior of $χ_{3}^{\prime\prime}$, $χ_{5}^{\prime\prime}$, and $χ_{7}^{\prime\prime} $ below $T_{cl}$ is related to the nonlinear behavior arising from the thermally activated flux flow.