The self-energy of the uniform electron gas in the second order of exchange

Abstract

The on-shell self-energy of the homogeneous electron gas in second order of exchange, $Σ_{2{\rm x}}= {\rm Re} Σ_{2{\rm x}}(k_{\rm F},k_{\rm F}^2/2)$, is given by a certain integral. This integral is treated here in a similar way as Onsager, Mittag, and Stephen [Ann. Physik (Leipzig) {\bf 18}, 71 (1966)] have obtained their famous analytical expression $e_{2{\rm x}}={1/6}\ln 2- 3\frac{ζ(3)}{(2π)^2}$ (in atomic units) for the correlation energy in second order of exchange. Here it is shown that the result for the corresponding on-shell self-energy is $Σ_{2{\rm x}}=e_{2{\rm x}}$. The off-shell self-energy $Σ_{2{\rm x}}(k,ω)$ correctly yields $2e_{2{\rm x}}$ (the potential component of $e_{2{\rm x}}$) through the Galitskii-Migdal formula. The quantities $e_{2{\rm x}}$ and $Σ_{2{\rm x}}$ appear in the high-density limit of the Hugenholtz-van Hove (Luttinger-Ward) theorem.