Charge Oscillations in Debye-Hueckel Theory

Abstract

The recent generalized Debye-Hueckel (GDH) theory is applied to the calculation of the charge-charge correlation function G_{ZZ}(r). The resulting expression satisfies both (i) the charge neutrality condition and (ii) the Stillinger-Lovett second-moment condition for all T and rho_N, the overall ion density, and (iii) exhibits charge oscillations for densities above a "Kirkwood line" in the (rho_N,T) plane. This corrects the normally assumed DH correlations, and, when combined with the GDH analysis of the density correlations, leaves the GDH theory as the only complete description of ionic correlation functions, as judged by (i)-(iii), (iv) exact low-density (rho_N,T) variation, and (v) reasonable behavior near criticality.