Compression of finite size polymer brushes

Abstract

We consider edge effects in grafted polymer layers under compression. For a semi-infinite brush, the penetration depth of edge effects $ξ\propto h_0(h_0/h)^{1/2}$ is larger than the natural height $h_0$ and the actual height $h$. For a brush of finite lateral size $S$ (width of a stripe or radius of a disk), the lateral extension $u_S$ of the border chains follows the scaling law $u_S = ξϕ(S/ξ)$. The scaling function $ϕ(x)$ is estimated within the framework of a local Flory theory for stripe-shaped grafting surfaces. For small $x$, $ϕ(x)$ decays as a power law in agreement with simple arguments. The effective line tension and the variation with compression height of the force applied on the brush are also calculated.