A numerical ab initio study of harmonic generation from a ring-shaped model molecule in laser fields

Abstract

When a laser pulse impinges on a molecule which is invariant under certain symmetry operations selection rules for harmonic generation (HG) arise. In other words: symmetry controls which channels are open for the deposition and emission of laser energy---with the possible application of filtering or amplification. We review the derivation of HG selection rules and study numerically the interaction of laser pulses with an effectively one-dimensional ring-shaped model molecule. The harmonic yields obtained from that model and their dependence on laser frequency and intensity are discussed. In a real experiment obvious candidates for such molecules are benzene, other aromatic compounds, or even nanotubes.