Virial relations for the Dirac equation and their applications to calculations of H-like atoms

Abstract

Virial relations for the Dirac equation in a central field and their applications to calculations of H-like atoms are considered. It is demonstrated that using these relations allows one to evaluate various average values for a hydrogenlike atom. The corresponding relations for non-diagonal matrix elements provide an effective method for analytical evaluations of infinite sums that occur in calculations based on using the reduced Coulomb-Green function. In particular, this method can be used for calculations of higher-order corrections to the hyperfine splitting and to the g factor in hydrogenlike atoms.