Finite-field evaluation of the Lennard-Jones atom-wall interaction constant C3 for alkali-metal atoms
W. R. Johnson, V. A. Dzuba, U. I. Safronova, M. S. Safronova
Abstract
A finite-field scaling method is applied to evaluate the Lennard-Jones interaction constant C3 for alkali-metal atoms. The calculations are based on the relativistic single-double (SD) approximation in which single and double excitations of Dirac-Hartree-Fock wave functions are included to all orders in perturbation theory.
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