Scaling laws for the photo-ionisation cross section of two-electron atoms
Abstract
The cross sections for single-electron photo-ionisation in two-electron atoms show fluctuations which decrease in amplitude when approaching the double-ionisation threshold. Based on semiclassical closed orbit theory, we show that the algebraic decay of the fluctuations can be characterised in terms of a threshold law σ |E|μ as E 0- with exponent μ obtained as a combination of stability exponents of the triple-collision singularity. It differs from Wannier's exponent dominating double ionisation processes. The details of the fluctuations are linked to a set of infinitely unstable classical orbits starting and ending in the non-regularisable triple collision. The findings are compared with quantum calculations for a model system, namely collinear helium.
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