Interplay of creation, propagation, and relaxation of an excitation in a dimer

Abstract

Interplay of simultaneous creation, annihilation, propagation, and relaxation of an excitation in molecular condensates interacting with an ultrashort quantum optical pulse is studied in general and specialized to a dimer. A microscopic model appropriate for such systems (with strong exciton-phonon coupling) is presented. It also incorporates effects of (quantum) noise in the optical field. A variety of new features in the initial stage of excitation dynamics (when it is being created) is revealed; a strong influence of the coherent excitation propagation on the processes of excitation creation and annihilation in a molecule strongly interacting with phonons is the most remarkable one.