Mori-Zwanzig formalism: An existence proof for weak solutions of the orthogonal dynamics equation

Abstract

In classical statistical physics, the Mori-Zwanzig projection operator technique is used to derive generalized Langevin equations for a random variable (observable). Standard derivations implicitly assume the existence of solutions to the so-called orthogonal dynamics equation as well as the validity of the variation of constants formula (Dyson identity). It was pointed out by Givon, Hald and Kupferman that the existence is a subtle issue for infinite-rank projections such as Zwanzig's projection [D. Givon, O. H. Hald, R. Kupferman, Israel Journal of Mathematics, 145 (221-241), 2005]. The authors proved the existence of weak solutions for Zwanzig's projection in the context of stationary Hamiltonian systems. To this date, this is the only existence proof that allows for an infinite-rank projection, whereas the uniqueness and regularity remain open problems. In this article, we generalize the existence proof by Givon et al. to nonstationary non-Hamiltonian systems whose time evolution is given by a quasicontraction semigroup. We establish growth bounds as well as the uniqueness for sufficiently regular solutions (if existent). Finally, we apply our results to Zwanzig's projection using the damped harmonic oscillator as an example.