Onsager-variational-principle-based Lattice Boltzmann Model For Three-phase Dielectric Fluid Flows

Abstract

Multiphase electrohydrodynamic (EHD) flows play a crucial role in various engineering applications. However, existing numerical studies on three-phase electrohydrodynamic systems predominantly rely on phenomenological models, often neglecting thermodynamic consistency and critical surface charge convection mechanisms. To address these fundamental gaps, this paper proposes a thermodynamically consistent three-phase EHD model derived strictly from the Onsager variational principle. This theoretical framework intrinsically guarantees thermodynamic consistency and accurately captures complex multiphysics interactions without requiring a priori assumptions. Furthermore, a mesoscopic lattice Boltzmann method is developed to solve the proposed model, enabling the natural capture of interfacial evolution and charge transport. The accuracy of the numerical framework are rigorously validated against several benchmark cases, including electroosmotic flow in microchannels, the spreading of a three-phase liquid lens, the equilibrium of static compound droplet, and the deformation of compound droplet under uniform electric field. Using this validated framework, we investigate EHD applications, specifically simulating the complex dynamics of double droplet coalescence and separation under electric field, as well as the behavior of droplets subjected to combined EHD and shear flow. Overall, this work provides a robust, thermodynamically reliable numerical tool for exploring the highly nonlinear behaviors of multiphase EHD systems.