A Broken Clock Is Right Twice a Day: [Ce/Mg] Is Not a Universal Chemical Clock

Abstract

The ratio of $s$-process to $α$-element enrichment ($[s/α]$) has been proposed as a ``chemical clock,'' or a means to estimate stellar ages. However, the age--$[s/α]$ relation varies with metallicity and location in the Galaxy, and the observed trends are not well predicted by galactic chemical evolution models. We quantify the age--[Ce/Mg] correlation across the Galactic disk in roughly 100,000 red giant stars observed with APOGEE in the SDSS-V Milky Way Mapper survey. We find that the slope of the correlation varies significantly with metallicity and guiding radius in the chemical thin disk. The trend is steepest in the outer disk and below Solar metallicity, while the most metal-rich stars and those in the inner disk show no correlation with age. In contrast, [Ce/Mg] patterns in the chemical thick disk are consistent across the Galaxy. Halo stars have higher [Ce/Mg] than the chemical thick disk, suggesting that asymptotic giant branch (AGB) enrichment is important even at low metallicity. Overall, patterns in [Ce/Mg] trace both the local star formation history and AGB nucleosynthesis. The complex interplay between [Ce/Mg], age, metallicity, and Galactic position means that [Ce/Mg] (and by extension $[s/α]$) is not a universal chemical clock.