Influence of Many-Body Dipole-Dipole Interactions on Excitation Transfer in a Dense Gas

Abstract

We study non-radiative dipole-dipole induced excitation transfer in dense Rb vapour. We show that density dependence of characteristic time of the excitation diffusion changes from linear to non-linear for high Rb density. It is attributed to the breakdown of binary collisions approach to the dipole-dipole excitation transfer. It is shown that the observed result can be qualitatively described if the mean free path is replaced by mean interatomic distance for the chracteristic diffusion length.