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Exact branch-transfer criterion for common-mode Thomson heat cancellation in thermoelectric couples

Peng Kang, Da Wan, Shulin Bai, Wei Yin, Peng Wang, Chenglong Wen, Zhen Li, Yu Liu, Lei Zheng, Li-Dong Zhao

cond-mat.mtrl-sciarXiv:2608.27519

Abstract

Thermoelectric p- and n-type legs are commonly paired by matching their Seebeck magnitudes, although a cooler responds to heat transported through its complete electrical and thermal network. We decompose the leg coefficients into differential thermopower α=Sp-Sn and common thermopower M=(Sp+Sn)/2. In a connected steady-state scalar thermoelectric network, a temperature-independent co-shift applied to every electrically active segment is an exact terminal null. A temperature-dependent perturbation of the legs relative to fixed leads is instead physical. At fixed current and shared isothermal endpoints, its first-order cold-port response is the action of Γm=T\,dm/dT on the difference between the p- and n-branch oriented collection measures. We prove that every continuous Γm cancels if and only if these measures are equal. In the constant-property, linear-common-mode limit, matching Ri/Ki leg is sufficient and does not require identical legs. One- and two-dimensional calculations confirm the analytic reductions within their stated domains. For split thermal pads, the analysis gives the exact array law ΔQc,Σ=Σj CjIjΔTc,j and, for series elements with isothermal hot pairs, IΔVΣ=-ΔQc,Σ. A representative seven-pair model gives corresponding increments of 7.87 mW and -2.80 mV. Branch transfer and endpoint topology therefore provide distinct material-pairing and device-test criteria for common-mode Thomson heat.

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