High-Resolution Dynamical Eigenspectroscopy via Variational Trotter Compression on a Superconducting Qubit Processor

Abstract

The pursuit of high-resolution eigenspectroscopy on noisy intermediate-scale quantum devices is often hindered by the trade-off between circuit depth and coherence time. In this work, we introduce and experimentally demonstrate a dynamical eigenspectroscopy protocol that extracts fine-grained energy structures from time-dependent survival amplitudes. To overcome the finite coherence window of current superconducting processors, we employ Variational Trotter Compression (VTC) as a practical means to extend the duration of high-fidelity unitary evolution. Using a multi-connected 9-qubit superconducting processor, we reconstruct the time-domain autocorrelation signal via quantum state tomography for the H2 molecule at different bond lengths and for the Fermi-Hubbard model across different correlation regimes. Through multi-frequency fitting and Fourier analysis, the extracted eigenenergies agree with the exact-diagonalization values to within 2x10^-3, including the near-degenerate levels in the strongly interacting regime. Our results establish experimental dynamical spectroscopy as a robust and generalizable framework for simulating both quantum chemistry and strongly correlated lattice systems, bridging weak- and strong-coupling regimes on near-term quantum hardware.