Quantum hot carrier spectra in plasmonic catalysis

Abstract

Vibrational activation of admolecules on metal nanoparticles is an elementary step in plasmonic catalysis, yet the underlying dynamics driven by hot carriers is not fully understood in the quantum regime. Using an atomistic description of plasmonic hot carrier generation, we investigate vibrational excitation and dissociation of oxygen on silver nanoparticles as a function of diameter D. As D reduces from the classical to quantum-sized regime, quantized distribution of hot carriers emerges with increasing population in the high-energy regions. These highly energetic hot carriers deliver more efficient vibrational coupling and dissociation. The rate of vibrational excitation shows a linear 1/D scaling, which results from Landau damping. It turns nonlinear at elevated light intensities due to vibrational heating generated by multiple electron scattering. The finding of quantized distribution of hot carrier in plasmonic catalysis opens new avenues for selective control and nonthermal energy conversion.