Stationary states for a particle in a box with slanted walls

Abstract

The quantum mechanical problem of a particle in a infinite potential well with slanted walls is studied. The energy eigenvalues are determined by a transcendental equation involving the Airy function of the first kind. Two limiting cases are discussed. Next, the allowed energies are found by graphical and numerical methods. The graphical analysis hints that for large quantum numbers the consecutive energy levels get arbitrarily close together. This asymptotic behavior of the energy spectrum actually holds, as shown by means of an intuitive argument and confirmed by resorting to basic properties of Airy functions. In a sense, Bohr's correspondence principle is more accurately fulfilled than in the cases of the standard particle in a box or the harmonic oscillator. A state is regarded the more confined the less the probability of finding the particle in the classically forbidden region. For some stationary states the confinement degree is calculated and a comparison is made with the harmonic oscillator, for which the ground state is the least confined of all stationary states. In the symmetric case --- right and left walls of equal slope --- something unexpected happens: beyond a certain critical slope the ground state is no longer the least confined eigenstate. Over and above its interesting physical features, this problem provides students with the opportunity to get acquainted with Airy functions, which do not belong to the standard mathematical repertoire of physics undergraduates.