Correlative effects of induced magnetic field-buoyancy on reactive solute dispersion dynamics in couple-stress fluids

Abstract

We investigate the dispersion of a reactive solute in a couple-stress fluid flowing between two parallel plates under the combined effects of pressure-driven flow, buoyancy, and an induced magnetic field. The model incorporates first-order heterogeneous reactions at both channel walls alongside a bulk reaction. Using Mei's multiscale homogenization technique accurate to third order, we develop a higher-order asymptotic formulation to determine the effective longitudinal dispersion coefficient and concentration field. Analytical predictions are complemented by Brownian dynamics simulations and finite-difference solutions, while the Aris method of moments quantifies transient mean displacement, spatial variance, and effective dispersivity. The hydrodynamic analysis reveals a singular branch in the velocity solution when the Hartmann number equals half the couple-stress parameter and identifies a characteristic quarter-power scaling between the Hartmann number and couple-stress parameter, separating couple-stress- and magnetically dominated regimes. The model recovers classical Taylor-dispersion behavior in the non-reactive Newtonian limit and agrees well with experimental measurements. Couple-stress rheology and magnetic damping suppress shear-induced dispersion, whereas buoyancy enhances dispersion through additional transverse velocity gradients. A distinct saturation regime of the dispersion coefficient emerges with an increasing couple-stress parameter, while unequal wall absorption induces persistent transverse asymmetry, and stronger absorption enhances solute removal near the source. Numerical and stochastic results validate the analytical framework while resolving higher-order concentration structures and particle-scale wall adsorption.