Raman scattering in cuprate oxychlorides high-temperature superconductors single-crystals

Abstract

We investigate the Raman response of sodium-doped cuprate oxychloride Na$_x$Ca$_{2-x}$CuO$_2$Cl$_2$ high-temperature superconductors across their entire phase diagram, from the antiferromagnetic to the superconducting region. In addition to the expected Raman-active phonon modes, we detect several additional modes that can be interpreted as being excited via a resonance process enabled by strong electron--phonon coupling. To verify the resonance effect, the Raman response at different incident photon energies was measured. At high energies, there is a well-defined $B_{1g}$ mode in the antiferromagnetic phase, which can be interpreted as a bimagnon We follow its temperature and doping dependence, providing information on the multimagnon excitation in these cuprates, which can be theoretically linked to the exchange interaction.