Attosecond circular-dichroism spectroscopy of hole ring currents

Abstract

Ultrafast ionization of atoms by circularly polarized few-cycle laser pulses generates a hole ring currents, offering a route for ultrafast manipulation of magnetism. Here we explore the subcycle formation of these currents whose circulation direction is determined by the driving-field helicity, whereas their magnitude is governed by the quantum coherence of the residual ion. We show that the correlated ion-photoelectron dynamics can be probed with attosecond transient-absorption circular dichroism. Using the Wigner-Eckart theorem, we derive a linear relation between state-resolved dichroic absorption and the orbital and spin angular-momentum projections of the hole, thereby extending the Thole-Carra magnetic CD sum rules from static X-ray spectroscopy to attosecond electron dynamics. The modulation depth of the dichroic signal provides a direct optical measure of the coherence injected by ionization, and its dependence on the pump-pulse duration reveals a competition between coherence build-up and ionization-induced dephasing. These findings demonstrate the potential of attosecond circular dichroism for probing ionic coherence and highlight the role of quantum coherence in ultrafast angular momentum exchange between light and matter.