Chemical complexity in feedback from supernova remnants: first detection of PO+ in IC443 and W44

Abstract

Supernova remnant (SNR) may shape the physical and chemical properties of star formation. By releasing refractory elements into the gas phase, they inject material of pre-biotic relevance into molecular clouds. Such elements may be inherited by planetary systems and become relevant for the emergence of life. We investigate the presence of P-bearing species in molecular clouds impacted by SNR-shocks. P is a crucial biological element, but its presence and reservoir in molecular clouds remain elusive. We present high-sensitivity 3 mm observations obtained with the IRAM 30m, toward the interaction sites between the SNRs W44 and IC443 and their associated molecular clouds. Focusing on PO+(2-1) and PN(2-1), we derive molecular column densities and abundances in local thermodynamic equilibrium. We investigate the correlation between P-bearing species and the shock tracer Silicon Monoxide (SiO). We detect, for the first time, PO+ toward SNRs, with abundances X(PO+)~8e-12-5e-11, but no significant PN emission. PO+ toward both SNRs is associated with strong SiO emission, showing similar linewidths but velocity offsets, suggesting that PO+ preferentially traces the most compressed and more strongly ionised layers of the shock. By comparing the derived abundances with those reported in literature, we suggest that the PO+ abundance mainly depends on a combination of shock strength and shocked medium density. Our results indicate that P-chemistry in SNR shocks is shifted toward an ion-dominated regime, likely driven by enhanced cosmic-ray ionisation rates. In this scenario, neutral species such as PN are efficiently destroyed, while ion-molecule reactions favour the production of PO+. This suggests that SNR shocks may play a role in processing P-bearing material and shaping gas-phase P chemistry in molecular clouds, with potential implications for the chemical inventory of star-forming environments.