Ideal gas of active particles in a box

Abstract

Extending a fundamental concept of thermodynamics to the nonequilibrium realm of active matter, we derive an ideal gas law for a suspension of noninteracting active particles confined to a finite rectangular box. The law is exact for run-and-tumble particles (RTPs) in one dimension and established by a systematic analytical expansion of the steady-state probability density for active Ornstein-Uhlenbeck particles in any dimension. It also agrees well with numerical results for active Brownian particles and RTPs in higher dimensions and recovers previously known relations for the limit of large system sizes. Together, these results demonstrate the applicability of the ideal active gas law to the three most widely studied theoretical models of colloidal active matter. As an application, we analyze thermodynamic processes involving active matter on a macroscopic level, without recourse to microscopic particle trajectories or self-propulsion fluctuations.