About the existence of the exotic molecular ions (HeH)2+ and He23+ in a strong magnetic field

Abstract

The Coulombic systems ( p e) and ( e), ( p p e), ( p e) and (Li3+ Li3+ e) placed in a magnetic field B 1011 G are studied. It is demonstrated a theoretical existence of the exotic ion (He H)2+ for B 5× 1012 G in parallel configuration (the magnetic field is directed along internuclear axis) as optimal as well as its excited states 1π, 1δ. As for the exotic ion He23+ it is shown that in spite of strong electrostatic repulsion of -particles this ion can also exist for B 100 a.u. (= 2.35× 1011 G) in parallel configuration as optimal in the states 1g (ground state), 1πu, 1δg. Upon appearance both ions are unstable towards dissociation with He+ in the final state but with very large lifetime. However, at B 10000 a.u. the ion (He H)2+ becomes stable, while at B 1000 a.u. the ion He23+ becomes stable. With a magnetic field growth, both exotic ions become more and more tightly bound and compact, their lowest rotational and vibrational energies grow. At the edge of applicability of non-relativistic approximation, B 4.414 × 1013 G, there are indications that three more exotic linear ions (H-He-H)3+, (He-H-He)4+ and even Li25+ in parallel configuration may also occur.

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