Experimental study of MgB2 decomposition
Z. Y. Fan, D. G. Hinks, N. Newman, J. M. Rowell
Abstract
The thermal stability of MgB2 has been studied experimentally to determine the role of thermodynamic and kinetic barriers in the decomposition process. The MgB2 decomposition rate approaches one monolayer per second at 650 C and has an activation energy of 2.0 eV. The evaporation coefficient is inferred to be ~ 10(-4), indicating that this process is kinetically limited. These values were inferred from in-situ measurements using a quartz crystal microbalance and a residual gas analyzer, in conjunction with ex-situ measurements of re-deposited material by Rutherford Backscattering Spectroscopy. The presence of a large kinetic barrier to decomposition indicates that the synthesis of MgB2 thin films conditions may be possible with vacuum processing, albeit within a narrow window in the reactive growth conditions.
Create a lesson
Related papers
Superconductivity in Pb2-xBixPd Single Crystals
S. Srivastava, R. P. Singh
Type-I superconductivity in a quasi-2D topologically nontrivial YbBi2
Karolina Górnicka, Sudip Malick, Joanna Bławat et al.
Generic thermodynamics of condensates with extremely small superfluid density ---Application to UTe2 and hidden second phase transition---
Kazushige Machida
Vortex-mediated spin current injection into two-dimensional superconductor NbSe2
Meng Yang, Xiaolong Yin, Jingjing Liu et al.
Superconductivity at the metal-insulator phase boundary in a bulk nickelate at ambient pressure
Hyo-Bin Ahn, Xinglong Chen, Hong Zheng et al.
Crystallographic imperfections and exotic superconductivity of UBe13
Andreas Leithe-Jasper, Markus König, Yusei Shimizu et al.