Influence of the starting composition on the structural and superconducting properties of MgB2 phase

Abstract

We report the preparation of Mg$_{1-x}$B$_{2}$ (0$\le$x$\le$0.5) compounds with the nominal compositions. Single phase MgB$_{2}$ was obtained for x=0 sample. For 0$<$x$\le$0.5, MgB$_{4}$ coexists with &#34;MgB$_{2}$&#34; and the amount of MgB$_{4}$ increases with x. With the increase of x, the lattice parameter ${\it c}$ of &#34;MgB$_{2}$&#34; increases and the lattice parameter ${\it a}$ decreases, correspondingly T$_{c}$ of Mg$_{1-x}$B$_{2}$ decreases. The results were discussed in terms of the presence of Mg vacancies or B interstitials in the MgB$_{2}$ structure. This work is helpful to the understanding of the MgB$_{2}$ films with different T$_{c}$, as well as the Mg site doping effect for MgB$_{2}$.